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Polyoxometalate-based coordination frameworks for CH4 generation in photoreduction of CO2

Researchers have developed polyoxometalate-based coordination frameworks that selectively reduce CO2 to methane with high photocatalytic activity. The integration of polyoxometalates and metalloporphyrin coordination frameworks enhances the reduction efficiency, allowing for the efficient conversion of CO2 to a valuable hydrocarbon fuel.

SourceScience China Press·JournalNational Science Review·DateAug 5, 2019

One-two-punch catalysts trapping CO2 for cleaner fuels

Scientists at DGIST have created a new photocatalyst that can convert sunlight into hydrocarbon fuels with improved efficiency. The addition of copper and platinum nanoparticles enhances the catalyst's ability to recycle atmospheric carbon dioxide., Researchers aim to further improve the technology to make it commercially viable.

SourceDGIST (Daegu Gyeongbuk Institute of Science and Technology)·JournalEnergy & Environmental Science·DateJun 7, 2019

Scientists develop metal-free photocatalyst to purify pathogen-rich water in minutes

Researchers from Yangzhou University and the Chinese Academy of Sciences create a metal-free photocatalyst that can purify pathogen-rich water in 30 minutes with over 99.9999% disinfection efficiency under visible light irradiation. The catalyst's high activity and low ecotoxicity make it a promising approach for global clean water sca...

Reducing CO2 with common elements and sunlight

A new photocatalyst composed of an organic semiconductor material and an iron complex selectively reduces CO2 to CO under visible light, converting the major factor of global warming into a valuable carbon resource. The efficiency of this process is comparable to that of precious metal or rare metal complexes.

SourceTokyo Institute of Technology·JournalJournal of the American Chemical Society·DateJun 25, 2018

Solar-to-hydrogen conversion: Nanostructuring increases efficiency of metal-free photocatalysts by factor 11

Researchers developed nanostructured polymeric carbon nitrides as catalysts for hydrogen production, increasing efficiency under visible light irradiation. The nanostructure with large pores and specific functionalities improved the catalytic properties, approaching that of inorganic catalysts.

SourceHelmholtz-Zentrum Berlin für Materialien und Energie·JournalEnergy & Environmental Science·DateFeb 28, 2018

Making hydrogen fuel from humid air

A team of researchers has created a photocatalyst that can generate hydrogen from water vapor using sunlight, producing the fuel without electrolytes or external power sources. The novel paint-like material can be applied to any surface, including building facades, and enables hydrogen production almost anywhere.

SourceAmerican Chemical Society·JournalACS Nano·DateJun 14, 2017

New carbon nitride material coupled with ruthenium enhances visible-light CO2 reduction in water

A new nanomaterial capable of reducing CO2 with high selectivity and turnover number has been developed by Tokyo Tech. The material consists of carbon nitride nanosheets combined with a metal structure known as binuclear ruthenium(II) complex, resulting in unprecedented binding of RuRu' to the nanosheet surface.

SourceTokyo Institute of Technology·JournalAngewandte Chemie International Edition·DateJun 12, 2017

New photocatalyst speeds up the conversion of carbon dioxide into chemical resources

A new titania photocatalyst has been developed to convert carbon dioxide into methane three times more efficiently than existing catalysts. The photocatalyst's controlled band gap improves light absorption and charge separation, increasing the conversion rate of CO2 into methane.

SourceDGIST (Daegu Gyeongbuk Institute of Science and Technology)·JournalApplied Catalysis B Environment and Energy·DateMay 26, 2017

Photocatalyst makes hydrogen production 10 times more efficient

Researchers at Kobe University have developed a new photocatalyst that increases hydrogen production tenfold. By deliberately creating a lack of uniformity in size and arrangement of crystals, the team was able to spatially separate electrons and holes, preventing recombination and increasing conversion efficiency.

SourceKobe University·JournalAngewandte Chemie International Edition·DateMay 18, 2017

Chemists challenge conventional understanding of how photocatalysis works

A team of chemists at UC Riverside proposes a new model explaining the promoting effect in photocatalysis, suggesting that excited electrons promote hydrogen reduction on the semiconductor surface rather than transferring to metals. This radical approach could lead to the development of more economical and efficient photocatalysts.

SourceUniversity of California - Riverside·JournalProceedings of the National Academy of Sciences·DateMay 19, 2014

Algal protein gives boost to electrochemical water splitting

Researchers have successfully created a nano-bio PEC electrode, consisting of iron oxide conjugated with a protein from blue-green algae, which is twice as efficient in water splitting as iron oxide alone. The use of phycocyanin, a light-harvesting protein, improves the electrode's ability to absorb photons and generate photocurrent.