Molecular sieve membrane-based separation technology, featured with low energy consumption and small carbon footprint, has attracted much attention in gas separation.
Metal-organic frameworks (MOFs) are promising in gas separation membranes due to their diversified structures, high porosity and tailored functionalities. However, defect-free MOF membrane fabrication still remains challenging.
Recently, a research group led by Prof. YANG Weishen and Dr. PENG Yuan from the Dalian Institute of Chemical Physics (DICP) of the Chinese Academy of Sciences (CAS) has fabricated flexible soft-solid MOF composite membrane on commercial polyvinylidene fluoride (PVDF) substrate.
Within the membrane structure, the quasi-vertically oriented, solid Zn 2 (Benzimidazolate) 4 particles grown on PVDF substrate provided predominant molecular sieving gas entrances while soft polyamide eliminated defects enclosing MOF particles, resulting in better performance in H 2 /CO 2 separation.
This work was published in Angew. Chem. Int. Ed. on Feb. 1.
This robust defect-free composite membrane exhibited an outstanding anti-swelling capacity in condensable feedstock. It showed superior separation accuracies for large C 2 H 6 and C 3 H 8 exclusions.
Moreover, the researchers prepared the Zn 2 (Bim) 4 composite membrane with ultra-high MOF loading and excellent flexibility. After membrane folding and unfolding at 90° for 50 consecutive times or rolling into a tube with a diameter of 3 mm (the largest bending curvature that MOF membranes can endure), the membrane separation performance remained exactly the same.
Soft-solid Zero Insertion Force(ZIF)-67 and ZIF-8 composite membrane series were also fabricated. Taking advantages of defect elimination, the intrinsic molecular sieving capacities of the MOF particles were given full play.
This work was supported by the National Natural Science Foundation of China.
Angewandte Chemie International Edition
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Flexible Soft-Solid Metal–Organic Framework Composite Membranes for H2/CO2 Separation
1-Feb-2022