Articles tagged with Chemical Reactions
Copper sulfide catalysts reconstruct their surface during Potential-Step electrolysis, producing compounds like formic acid and suppressing hydrocarbon formation. Sulfur and oxygen play distinct roles, promoting hydrogen adsorption and generating neighboring Cu0/Cu+ sites for carbon–carbon bond formation.
Researchers used 3D electron microscopy to capture direct evidence of electric fields at air-water interfaces, opening a path to rationally designed clean-energy materials. The study found a repulsive force holding thinnest films together, reaching 10 megapascals, and provided chemical evidence for the electric field's existence.
Researchers found that lab variations can lead to inconsistent data, affecting AI model accuracy and reproducibility. The study highlights the importance of standardization in experimental design to improve data quality for machine learning models.
SNU researchers developed a new catalyst design principle that selectively suppresses hydrogen evolution while maintaining nitrogen reduction activity. The approach increased Faradaic efficiency to nearly 100% and enables localized production of eco-friendly ammonia near renewable energy sources.
Researchers at TU Wien developed a novel catalyst converting nitrate from wastewater into ammonia using sunlight and electricity. The MXene-Gold material interacts optimally, capturing light and heat while facilitating chemical reactions.
Researchers at UC Riverside develop a catalyst that effectively breaks down perchlorate at high concentrations, potentially reducing hazardous waste generated during drinking water treatment. The breakthrough technology could make it possible to destroy perchlorate after it has been captured on ion-exchange resin.
Researchers at Penn State found that adjusting the atomic arrangement of structural metals in molten salt reactors can significantly affect corrosion rates. The study's findings highlight the importance of material stability and chemical interactions between salts, metals, and mechanical stress.
Researchers have identified a quantum phenomenon that enables molecular dissociation with significantly less energy than normal. The discovery, published in Physical Review Letters, reveals that electromagnetic vacuum fluctuations can promote molecular vibrations and break chemical bonds when molecules are confined in nanocavities.
Researchers at Texas A&M University develop a laser technique called TRIP to directly measure quantum forces shaping proteins, enabling accurate prediction of how pharmaceutical drugs interact with them. This breakthrough could lead to the design of medicines tailored to specific diseases, revolutionizing precision medicine.
Researchers develop Csp–π–d conjugated system to enhance oxygen reduction performance, outperforming platinum-based catalysts in stability and cost-effectiveness. The new catalyst facilitates electron transfer and weakens OH adsorption, promoting intermediate desorption and accelerating reaction kinetics.
A self-driving chemistry lab called Flex-Cat has been developed to autonomously search for faster and more selective ways to make important industrial chemicals. The platform combines robotics, high-pressure reactors, and artificial intelligence to identify high-performing catalysts and those that can be programmed to produce different...
Yang's research group and collaborators develop a new reaction mechanism that employs photochemistry and metalloenzyme catalysis to form carbon-carbon bonds. This method enables the creation of molecules with multiple stereogenic centers, crucial for pharmaceuticals and agrochemicals.
Scientists at TU Wien have designed a new sustainable route to ammonia synthesis using metal-organic frameworks (MOFs) as catalysts. By tuning the MOF structures, they can modulate their catalytic performance, providing valuable insights into more efficient and sustainable ammonia-production technologies.
Researchers developed a system to link polyphenol chemical structures with bitterness, acidity, and astringency. Polyphenols found in tea, cocoa, and other foods influence taste sensations, affecting food preferences and digestive responses.
A deep learning model combines knowledge from different catalyst families to identify a top-performing green hydrogen catalyst. The AI correctly predicted the activity ranking of 12 tested catalysts within a previously unexplored material family.
FAU engineering researcher Masoud Jahandar Lashaki has been awarded a prestigious NSF CAREER award to study the oxidative degradation of amine-functionalized sorbents. The project aims to design longer-lasting technologies for capturing pollutants from air and water, improving indoor and outdoor air quality.
Researchers at Nagoya University have developed a new method called SMART that accelerates enzyme evolution and reduces costs by accelerating the selection period from weeks to days. The system uses mRNA display, next-generation sequencing, and bioinformatics to identify superior enzyme variants.
Researchers at University of Wisconsin-Madison develop a systematic study for sustainable production of malonic acid via oxidation of 3-hydroxypropionic acid with a Pd/Carbon catalyst. The kinetic model validated the network, displaying excellent agreement and providing insight into conditions that maximize MA production.
Researchers at Chiba University have found that a balance between photocatalytic and photothermal processes is necessary for efficient CO2 conversion. The team achieved high rates of CO2-to-methane conversion by controlling temperature and light intensity, providing a pathway toward designing more efficient catalysts.
The researchers developed an AI-based method that allows users to input natural language prompts about the materials they want to create and suggests optimal procedures for experiments to produce them. The method has been successfully applied to identify catalysts for turning carbon dioxide and hydrogen into carbon monoxide and water u...
Nagoya University researchers have developed an iron-based alternative to expensive chiral ligands in metal-based photocatalysts, achieving a precise radical cation cyclization and the first total asymmetric synthesis of (+)-heitziamide A using blue LED light and abundant iron.
Researchers at Tohoku University have developed a new technology that uses thioguanosine to achieve highly efficient and controllable interstrand crosslinking of DNA. This breakthrough enables reversible DNA modification with high stability and reversibility, opening opportunities for next-generation bionanomaterials.
Researchers at the University of Rochester have developed a new way to harness the properties of tungsten carbide as a catalyst for producing valuable chemicals and fuels. The method, which involves carefully manipulating tungsten carbide particles at the nanoscale level, has shown promising results in reducing costs and increasing eff...
Scientists successfully observed a quinoxalinyl radical forming within nanoseconds using µSR spectroscopy. The technique enabled real-time detection of highly reactive aromatic heterocyclic radicals in isocyanide insertion reactions.
Hua Bai and Sheng Dai, faculty members at the University of Tennessee, have been elected National Academy of Inventors (NAI) Fellows for their innovative research in power electronics and advanced materials. Their work has led to significant advancements in electrical vehicle technology and energy-related applications.
Scientists at the University of Michigan have developed a theoretical framework that shows how to create soft, elastic, and lightweight materials with active features. The model proposes coupling material mechanics and chemistry to overcome natural damping behavior and achieve chaotic motion.
Scientists at TU Wien have created an alternative production method for Cu-64, a crucial copper isotope used in medicine. By harnessing recoil chemistry and utilizing a specially designed metal–organic complex, they can efficiently separate the desired isotope from ordinary copper.
Researchers at the University of Illinois have developed a new theoretical framework that replaces traditional computational models used in quantum chemistry. The new method, which uses an independent atom reference state, provides a more elegant and computationally affordable alternative for predicting chemical reaction energetics.
A study from OIST shows that abrasion from common additives can lead to efficient reactions under mechanochemical conditions. Abrasive materials like tungsten carbide or diamond powder activate catalysts and drive coupling reactions. This finding changes the way researchers think about mechanochemical catalysts.
Scientists at OIST have created crystal-free films of photoluminescent compounds that exhibit mechanoluminescence when stimulated through mechanical forces. This breakthrough removes the need for complex crystal design and engineering in creating mechanoluminescent materials.
A team of researchers from Worcester Polytechnic Institute has developed a new approach to producing hydrogen using plasma technology and metal alloys. The method reduces energy consumption and carbon emissions compared to traditional methods, making it more environmentally friendly and potentially affordable.
Researchers at CARS create detailed maps of chemical reactivity, discovering regions of unexpected outcomes and reconstructing intricate reaction networks. This new understanding enables control over the formation of different major products from a set of starting materials.
Researchers at the University of Maine Forest Bioproducts Research Institute have discovered a sustainable method to produce (S)-3-hydroxy-γ-butyrolactone, a crucial building block in pharmaceuticals. This approach could significantly reduce greenhouse gas emissions and production costs by up to 60%.
A new study has revealed chemical signatures of ancient Martian microbial life in the Bright Angel formation, a region of Jezero Crater known for its fine-grained mudstones rich in oxidized iron and organic carbon. The findings suggest that early microorganisms may have played a role in shaping these rocks through redox reactions.
Researchers at the University of Pennsylvania have discovered a way to synthesize new multi-metal 2D materials by adding up to nine metals into the mix. This finding opens up possibilities for designing materials with precisely controlled properties for diverse applications.
A team of researchers has discovered a novel oxide material that can produce high-efficiency clean hydrogen using only heat. The discovery was made possible by a new computational screening method and has the potential to transform industries such as methane reforming and battery recycling.
Researchers at Chiba University developed a method for selectively attaching an alkyl group to the C5 position of indole using a copper-based catalyst, producing yields of up to 91%. This approach could enable more affordable and scalable modification of indoles, crucial for drug development.
Researchers discovered a new 'In and Out' mechanism where CO₂ briefly dips into the topmost layer of water, reacts, and then reemerges. This challenges previous assumptions about where and how CO₂ can turn into carbonic acid, suggesting faster ocean acidification.
Face masks degrade into nanoplastics under sunlight, changing their chemical nature and affecting ecosystems. Researchers found that exposure to sunlight is required for the formation of manganese oxide on plastic particles, altering their interaction and transport in the environment.
Scientists at SwRI conducted lab experiments to explain the mysterious distribution of hydrogen peroxide on Jupiter's icy moon Europa. The research found that trace amounts of CO2 in water ice can enhance hydrogen peroxide production, shedding light on the moon's habitability and chemical cycles.
Researchers used advanced techniques to study propylene electrooxidation on Pd and Pt catalysts, revealing that surface reconstruction governs reaction selectivity. The findings show that changes in the catalyst surface under working potentials determine which products are formed.
A USC-developed shipboard system using limestone and seawater can remove up to half of carbon dioxide emitted from shipping vessels, cutting maritime CO2 emissions by 50%. The process mimics a natural chemical reaction in the ocean, where CO2 is absorbed into water pumped onboard and then neutralized through a bed of limestone.
Scientists developed an algorithm that can accurately simulate atomic interactions on material surfaces, reducing the need for massive computing power. This breakthrough enables the analysis of complex chemical processes in just two percent of unique configurations, paving the way for improved battery performance.
Researchers developed a technology that precisely analyzes 21 types of reactants simultaneously using high-resolution fluorine nuclear magnetic resonance spectroscopy. This breakthrough contributes to new drug development and catalyst optimization in AI-driven autonomous synthesis.
Researchers developed a novel MoS2-confined Rh-Fe dual-site catalyst for the direct conversion of methane to acetic acid, achieving an unprecedented CH3COOH selectivity of 90.3% at room temperature. The catalyst's unique structure effectively balances C-H activation and C-C coupling, addressing long-standing challenges in this process.
Researchers at Pohang University of Science & Technology have developed a novel iron-based catalyst that more than doubles the conversion efficiency of thermochemical green hydrogen production. The new catalyst, iron-poor nickel ferrite (Fe-poor NiFe2O4), enables significantly greater oxygen capacity even at lower temperatures.
A team from The University of Osaka has developed an efficient non-precious metal catalyst for converting biomass-derived furfural to tetrahydrofurfuryl compounds, achieving high yields under mild conditions.
MIT engineers developed ultrathin electronic films that sense heat and other signals, reducing the bulk of conventional goggles and scopes. The new pyroelectric thin film is highly sensitive to heat and radiation across the far-infrared spectrum, enabling lighter, more portable night-vision eyewear.
A UT Health San Antonio-led discovery could redefine drug discovery by turning IV medications into orally administered treatments for brain cancer, Alzheimer’s disease, and other complex conditions. The new strategy uses a protein receptor called CD36 to efficiently deliver large molecules into cells.
Researchers have developed a new photopolymerisation reaction controlled by two different colours of light, enabling the creation of solid polymeric materials with resolutions below millimetres. This method allows for precise spatiotemporal control and could improve the performance of 3D printing processes.
Researchers have developed a new sensor to detect hazardous gas leaks in lithium-ion batteries, which could prevent catastrophic failures and enhance the reliability of battery-powered technologies. The sensor detects trace amounts of ethylene carbonate vapour, targeting potential battery failures before they escalate into disasters.
Scientists developed a novel solvatochromic fluorescent dye that enables high-precision temperature measurements through changes in fluorescence properties. The researchers achieved exceptional sensitivity and resolution, ideal for bioimaging applications.
Researchers have developed cost-effective and efficient water-splitting catalysts using cobalt and tungsten, which surprisingly increase in performance over time. The unique self-optimization process involves changes in the chemical nature of the catalyzing oxide, leading to improved activity and reduced overpotentials.
Genetic changes triggered by environmental factors like pollution, diet, and stress can increase cancer risk. Nearly everyone is exposed to cancer risk factors daily, highlighting the need for public awareness and policy action to reduce exposure.
New research suggests that volcanic activity billions of years ago accelerated oxygenation, leading to an increase in atmospheric oxygen. This pre-Great Oxygenation Event (GOE) may have provided the necessary conditions for photosynthetic microorganisms to thrive, ultimately paving the way for complex life.
A new study by MIT confirms the Antarctic ozone layer is healing, with high statistical confidence that reductions in CFCs are the primary cause. The research uses fingerprinting to isolate the anthropogenic signal and rule out natural variability.
Researchers have developed a palladium-mediated reaction to precisely modify peptides and proteins, overcoming challenges in bioconjugation. The method targets dehydroalanine-containing peptides and proteins, enabling efficient synthesis of structurally unique peptides.
A team of scientists has discovered that some key hydrofluoroolefins (HFOs) decompose into persistent greenhouse gas pollutants, including compounds banned internationally. The chemicals are used as refrigerants, aerosol propellants, and in foamed plastics.
Researchers found that ancient glaciers carved deep into the Earth's crust, releasing key minerals that altered ocean chemistry. This process created conditions that allowed complex life to evolve, with the influx of elements changing ocean chemistry at a critical time in evolution.
Researchers at NC State University have developed a new technique to tune the optical properties of quantum dots using light, reducing energy consumption and environmental impact. This method allows for precise control over the bandgap, enabling the creation of high-quality perovskite quantum dots for optoelectronic devices.