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Putting 2 and 2 together

The new cobalt-catalyzed [2π+2π] reaction overcomes limitations of other transition metal catalyzed methods, producing cyclobutane compounds with potentially beneficial properties. The research team used redox active bis(imino)pyridine ligands to pass electrons to and from the metal, leading to a detailed understanding of the mechanism.

SourcePrinceton University·JournalJournal of the American Chemical Society·DateJun 8, 2015

Better catalysts, made-to-order

University of Utah scientists develop computational model to predict catalyst performance, allowing for the design of more efficient and selective catalysts. The model uses big data analysis to identify structural features that correlate with reaction selectivity.

SourceUniversity of Utah·JournalScience·DateFeb 12, 2015

Fusion helped by collision science

Researchers applied Deutsch–Märk and Binary-Encounter-Bethe methods to beryllium and its derivatives. The calculations provide improved understanding of electron impact ionization cross sections (EICS) for the ITER fusion chamber.

SourceSpringer·JournalThe European Physical Journal D·DateJan 11, 2013

Rust never sleeps

Electron mobility in iron oxide is crucial for understanding chemical reaction mechanisms, including uranium groundwater reactions and low-cost solar energy devices. The study reveals the rates of electron transport vary depending on iron oxide structure, with rates ranging from a single hop to five hops per nanosecond.

From pomegranate peel to nanoparticles

Researchers have developed a method to produce silver nanoparticles using pomegranate peel as a reducing agent, avoiding the use of harsh chemicals and industrial solvents. The process produces nanoparticles with a diameter of 5 nanometers and has potential applications in various fields.

SourceInderscience Publishers·JournalInternational Journal of Nanoparticles·DateJun 19, 2012

Electrochemistry controlled with a plasma electrode

Scientists at Case Western Reserve University create an electrochemical cell with a stable plasma electrode, allowing for controlled electron transfer and reducing losses. The technology has the potential to improve battery and fuel cell efficiency and enable new applications such as hydrogen production and nanomaterial synthesis.

SourceCase Western Reserve University·JournalJournal of the American Chemical Society·DateOct 19, 2011

Chemistry with sunlight

A new method combining electrochemistry and photovoltaics is being explored to clean up oxidation reactions. By harnessing solar energy, the need for toxic chemicals can be eliminated, reducing environmental harm. The research aims to make chemical synthesis more efficient and environmentally friendly.

SourceWashington University in St. Louis·JournalGreen Chemistry·DateJun 9, 2011

Scientists offer new view of photosynthesis

A research team led by Neal Woodbury has uncovered a new view of photosynthesis, revealing the orchestrated movement of proteins on a millionth of a second. This discovery helps explain why changing the energetics didn't knock out photosynthesis, and offers lessons for improving organic solar cells.

SourceArizona State University·JournalScience·DateMay 3, 2007

University of Oregon chemists discover new way to fix nitrogen

Researchers have successfully synthesized ammonia from nitrogen using a simple compound of iron and hydrogen in solution, marking a significant step toward achieving one of chemistry's coveted goals. This breakthrough could lead to more efficient and sustainable production of ammonia, a vital fertilizer for global food supply.

SourceUniversity of Oregon·JournalJournal of the American Chemical Society·DateJul 5, 2005

Novel chemistry induced by ultashort laser pulses

Researchers use ultrashort laser pulses to activate a critical surface reaction, allowing for the oxidation of CO molecules on transition metal surfaces. This novel approach enables the system to rapidly transfer energy into the oxygen-metal bond, outpacing desorption processes and unlocking new chemical pathways.

SourceMax-Planck-Gesellschaft·JournalScience·DateAug 13, 1999