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Yokohama National University


Core electron topologies in chemical bonding

A new benchmark quantum chemical calculation reveals a qualitative difference in the topologies of core electron orbitals between organic molecules and their silicon analogues. This discovery suggests that core electrons play a more significant role than previously thought, particularly in unsaturated compounds.

SourceYokohama National University·JournalAngewandte Chemie International Edition·DateJun 12, 2018

Photoreversible molecular switch changes the physical property of thermoresponsive polymer

Scientists at Yokohama National University developed a photoresponsive molecular switch that enables the control of sol-gel transitions in thermoresponsive polymers. The azobenzene-containing ionic liquid triggers reversible physical property changes upon light irradiation, showing tunable sol and gel states.

SourceYokohama National University·JournalAngewandte Chemie International Edition·DateFeb 1, 2018