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Chemists control supramolecules using vapors

Researchers design a vapor-controlled reversible host–guest chemistry system that controls the optical and physical properties of a functional molecular liquid. The FML's optical and physical properties change immediately upon forming a host–guest complex, but can be restored by exposing it to hexane vapors.

SourceInstitute of Transformative Bio-Molecules (ITbM), Nagoya University·JournalChemical Science·TypeExperimental study·DateJul 21, 2026

Physics-based predictive tool will speed up battery and superconductor research

Researchers from the University of Tokyo have developed a physics-based predictive tool that quickly identifies stable intercalated materials for advanced electronics and energy storage devices. By analyzing over 9,000 compounds, the tool uses straightforward principles from undergraduate chemistry to predict host-guest stability.

SourceInstitute of Industrial Science, The University of Tokyo·JournalACS Physical Chemistry Au·DateApr 1, 2024

A first for ferrocene: Organometallic capsule with unusual charge-transfer interactions

A ferrocene-based capsule with unusual charge-transfer interactions has been synthesized, allowing for reversible encapsulation and release of guest molecules. The capsule can bind to a variety of organic and inorganic dyes and electron-accepting molecules, demonstrating its potential applications in medicine, biotechnology, and chemic...

SourceTokyo Institute of Technology·JournalAngewandte Chemie International Edition·TypeExperimental study·DateAug 29, 2023

Modifying the structure to meet the demands

Recent developments in COFs' postsynthetic functionalization have introduced wide ranges of organic to inorganic functional constituents, enhancing stability and performance. The authors emphasize the importance of functionalization for creating COF-based smart materials, highlighting challenges in their future development.

SourceScience China Press·JournalNational Science Review·DateSep 18, 2019

Researchers improve bonding in mechanically linked molecules

Researchers have improved the bonding in mechanically linked molecules by developing a method to increase the association constant of host-guest interactions, allowing for longer self-assembled chains. By utilizing hydrogen bonding instead of covalent chemistry, they were able to overcome the difficulty of creating rigid macrocycles.