Research at Dalian Institute of Chemical Physics proposes hetero-lattice intergrown MOF membranes for efficient polyol dehydration. The novel membrane design achieves ultra-stability and high pervaporation performance, offering a potential solution to overcome separation challenges.
A new catalytic approach directly converts solid biomass into natural gas with a low carbon footprint, achieving nearly complete conversion of various agricultural and forestry materials. This process reduces fossil energy depletion and greenhouse gas emissions by up to 26% and 34%, respectively.
Researchers investigated the effect of temperature on Ionic-liquid-modified non-precious metal catalysts for oxygen reduction reactions, demonstrating that IL modification significantly increases ORR activity and stability, even at elevated temperatures. The study confirms the SCILL concept's potential in improving LTFCs.
Researchers highlight importance of digital microscale electrochemical energy storage devices in building a fully connected and intelligent world. They discuss design principles, material selection, and fabrication processes for these devices, which are crucial for seamless integration with various electronic systems.
Researchers create new route for producing PCTA monomer using plant-based acrylate and acetaldehyde, achieving overall yield of 61%. The method also produces UNOXOL diol in high yield, reducing carbon footprint.
Researchers developed a highly stable Cu-based catalyst with controlled SMSI at mild reduction temperatures, exhibiting ultra-stable performance over 500 hours at 600 °C. The catalyst's sintering was suppressed even at 800 °C.
Researchers develop highly efficient electrocatalytic hydrogenation of acetylene to ethylene under room temperature, using water as a hydrogen source and reducing energy consumption. The process achieves high Faradaic efficiency and selective ethylene production via electron-coupled proton transfer pathways.
Researchers from Dalian Institute of Chemical Physics discovered triboionization in a discontinuous atmospheric pressure interface, enabling analytes to be detected without an extra ionization source. By adjusting the pinch valve frequency, signal intensity was improved by nearly 20 times.
Scientists reveal an ultrafast and high-yield polaronic exciton dissociation mechanism in 2D perovskites, contradicting previous theories. This study confirms that free-carriers dominate charge carriers in 2D perovskites under room temperature.
A research team from Dalian Institute of Chemical Physics discovered the critical surface/interface behaviors governing ESDs' operation and failure. They visualized atmosphere-dependent relaxation and failure processes using in situ Raman, X-Ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS).
Researchers developed an in-situ imaging method to visualize electron transfer on metal nanoplates, revealing site-dependent heterogeneity. The study decoupled mass transfer effects and extracted rate constants, providing insights into electrocatalytic reactions.
Researchers have developed efficient catalysts for ammonia synthesis under mild conditions using ternary ruthenium complex hydrides. The unique configuration and function mechanism of these complexes enables non-dissociative activation of nitrogen, leading to superior kinetics and favored ammonia production.
Researchers have developed highly efficient flexible perovskite solar cells by annealing a SnO2 ETL in a rough vacuum at a low temperature, achieving 20.14% efficiency and improved interface connection.
Researchers developed a photocatalytic oxidative reforming process to convert bio-polyols into CO under ambient conditions. The Z-scheme catalyst structure facilitated adsorption and activation of dioxygen, promoting hydroxyl radicals and enhanced CO production rate.
Researchers at Dalian Institute of Chemical Physics observed the Marcus inverted region in charge transfer from low-dimensional semiconductor materials. This finding reveals a new understanding of the fundamental energetics dependence of electron transfer, benefiting energy conversion applications of these materials.
Researchers at Dalian Institute of Chemical Physics demonstrate vibrationally excited molecular hydrogen production from water photochemistry. This process represents a further source of vibrationally excited H2 observed in the interstellar medium.
A new iron-based perovskite material has been developed to intensify solar thermochemical CO2 splitting. The material achieves an unprecedented CO production rate of 381 mL g−1 min−1 with 99% CO2 conversion at 850 ºC, outperforming state-of-the-art materials.
A new approach controls the coffee ring effect in spray-coating, leading to high-performance perovskite solar cells with 19.17% power conversion efficiency. The reaction-dependent method uses solvent selection to regulate solute distribution and achieve uniform films.
Researchers from Dalian Institute of Chemical Physics designed a chainmail catalysis system for CO oxidation, achieving near 100% conversion at room temperature. The graphene-isolated Pt catalyst overcomes the issue of deep oxidation and enables efficient CO conversion.
Researchers found that Al atoms in FER-type zeolites are constrained at T1 and/or T3 sites, leading to inactive Brønsted acid centers. This limits the catalytic performance of FER-type zeolites compared to MOR-type zeolites.
Researchers developed an electrochemical strategy for hydrogenation of N-heterocycles over a bifunctional MoNi4 electrode, achieving high Faradaic efficiency and selectivity. The method uses water as a hydrogen source, avoiding flammable gases and toxic substances.
Researchers develop amide-linked covalent organic frameworks as efficient heterogeneous photocatalysts, improving adsorption capacity and recyclability for dyes in water. The frameworks exhibit high crystallinity and stability, ensuring satisfactory recyclability and outstanding photocatalytic activity under visible light.
Researchers developed a new strategy to achieve efficient and stable CO2 electrolysis in solid oxide electrolysis cells. They found that redox cycle manipulations promoted the exsolution of high-density metal/perovskite interfaces, improving performance and stability.
Dalian Institute of Chemical Physics researchers propose dual active site strategy to isolate dehydrogenation and oxidation in oxidative dehydrogenation of ethane, resulting in near 100% ethene selectivity. This approach could be extended to multiple oxidation reactions plagued by over-oxidation.
Researchers developed a novel catalyst, Ni-Mo2C/MCM-41, for efficient conversion of jatropha oil to high-grade biofuel. The catalyst achieved an 83.9% biofuel yield, showcasing its potential for improving catalytic performance in vegetable oil conversion.
A research group synthesized a Pb-alloyed Cu catalyst, showing high activity for electrochemical CO2 reduction with selectivity to formate. The study reveals a multi-path mechanism for CO2 reduction through COOH* and HCOO* intermediates.
A new methodology, EMARS, was developed to directly identify the activity origin of Pt/Al2O3 industrial reforming catalyst by analyzing over 18,000 Pt atoms. The study found that density of supported Pt1 single atoms and Pt-Pt distance larger than 0.38 nm are correlated with aromatic production activity.
Researchers synthesized a uniform Cu-N-C single-atom catalyst that exhibits comparable alkaline ORR activity to Pt/C. The active site structure undergoes dynamic changes during the reaction, transforming into HO-Cu-N2 under reaction conditions.
Researchers developed an earth-abundant Zr-H catalyst for selective hydroboration of primary, secondary, and tertiary amides. The reaction pathway involves unusual C-N bond cleavage-reforming followed by C-O bond cleavage, enabling efficient amine synthesis.
Researchers have developed Mo-doped Bi5O7Br nanosheets that significantly improve nitrogen reduction to ammonia under ambient conditions. The material's oxygen vacancies and Mo dopant facilitate N2 capture, activation, and fixation, leading to enhanced photoactivity.
Researchers develop efficient Ni-Co alloy nanoparticle catalysts for HDO reactions, achieving 100% selectivity and conversion efficiency. The synergistic effect of alloyed nanoparticles enhances deoxygenation activity and selectivity.
Researchers design a new strategy for producing pentanoic biofuels by synthesizing Ru metal nanoclusters confined within zeolite Y. This approach boosts chemoselectivity and promotes catalytic activity. The findings extend the notion of 'the closer, the better' into biomass catalysis.
Researchers developed highly-efficient chainmail catalysts for decoupled water electrolysis, producing hydrogen with low energy consumption. The device reduced the potential of hydrogen production by 1.24V, saving 60.2% energy compared to direct electrolysis.
High-energy-density Li–S batteries have been evaluated for their cycling lifespan, showing that considerable lithium polysulfides exist in the electrolyte despite high specific capacities. The actual capacity loss is mainly attributed to dissolved sulfur species rather than Li anode depletion.
A new membrane design reduces dendrite issues in zinc-based batteries, achieving high areal capacity and current density. The study demonstrates improved energy efficiency and stability at high current densities.
Researchers developed an efficient method for direct methanation of lignocellulosic biomass using Ru/TiO2 catalysts, achieving selectivity above 95% at temperatures below 200°C. The oxygen-vacancy-mediated catalysis process couples biomass oxidation with hydrogenation to produce biomethane.
The research found dramatically different quantum state population distributions of OH and OD fragments from HOD photodissociation. The branching ratios display large wavelength-dependent isotopic fractionation, influencing D/H isotope heterogeneity in the solar system.
A triphase air-liquid-solid photocatalytic system with a hydrophobic surface improves CO2 reduction efficiency by 8.8 times compared to water environments, thanks to enhanced CO2 transport and adsorption capabilities.
Researchers have identified distinct metabolic phenotypes in hepatocellular carcinoma subtypes, providing insights into precise personalized treatment options. The study revealed a poor prognosis subtype strongly correlated with immune pathway up-regulation and unsaturated fatty acid accumulation.
A new genetic engineering platform has been established in methylotrophic yeast Pichia pastoris, enhancing homologous recombination rates and genome editing efficiency. This breakthrough can enable the stable loading of over 100 exogenous genes and precise regulating of gene expression.
Researchers developed hybrid enzyme catalysts using a de novo approach to expand biocatalysis, improving stability and activity. The method involves introducing defects into MOFs to alleviate diffusional restrictions and facilitating access of substrates to encapsulated enzymes.
Researchers have developed a new method to build nitrogen- and phosphorus-containing compounds from feedstock chemicals using PcFe as a catalyst. The reaction offers high efficiency and yields up to 88% with a low activation energy of 4.8 kcal/mol.
This study introduces a Zr-doped Na3V2(PO4)2F3 coated with N-doped carbon, which improves SIB performance by increasing reversible capacity and rate capacity. The optimized electrode demonstrates excellent cycling stability.
The review discusses defect and interface engineering for e-NRR electrocatalysts, emphasizing active sites and intrinsic mechanisms. It highlights the potential strategies to develop more advanced NRR electrocatalysts, promoting the creation of more efficient catalysts for electrochemical nitrogen reduction.
A joint research team revealed the mechanism underlying the formation of the first carbon-carbon (C-C) bond during the methanol-to-olefins (MTO) process. They detected surface ethoxy species, a critical intermediate containing the initial C-C bond, and employed theoretical calculations to predict its formation.
A newly developed LDH-based composite membrane enhances AZIFB performance by improving selectivity and hydroxide ion conductivity. The study achieved an operating current density of 200 mA cm‒‒, along with high energy efficiency of 82.36%.
A team led by Prof. Peng Wu designed a structured, binder-free MWW-type titanosilicate catalyst that achieves high PO selectivity under mild reaction conditions, with a lifetime of 2400 hours and low solvent consumption.
Researchers developed Ru1/NC SAC, showcasing improved catalytic activity and selectivity in reductive amination reactions. The single-atom dispersion and coordination environment play crucial roles in determining the catalytic performance.
A bioinspired approach to C2 prenylation of indoles has been developed, enabling the regioselective synthesis of tryptophol and tryptamine derivatives. The method uses cheap tert-prenol as a precursor and Lewis acid AlCl3 as a catalyst, demonstrating high selectivity.
Researchers developed a novel solar energy-driven method to produce ethylene glycol (EG) from methanol, offering a sustainable and clean alternative. The catalyst, nitrogen-doped tantalum oxide, demonstrated high activity and stability for EG production, making it an environmentally friendly candidate for industrial applications.