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Polymer enables tougher recyclable thermoplastics

Cornell researchers created a chemically recyclable thermoplastic by synthesizing long polymer chains using a special catalyst. The resulting material, poly(1,3-dioxolane) or PDXL, has high tensile strength and can be easily depolymerized back to its monomer state, making it suitable for large-scale applications like packaging products.

SourceCornell University·JournalScience·DateAug 13, 2021

Polymerization process of hydrogel microspheres on video

The study used direct visualization to clarify the formation mechanism of microgels during precipitation polymerization. The research revealed that the aggregation of polymer chains in the nucleation process is crucial for determining the nanostructures of microgels, leading to improved understanding of their formation.

SourceShinshu University·JournalLangmuir·DateMar 2, 2021

Ultraheavy precision polymers

Researchers have developed a simple, environmentally friendly process to produce well-defined linear and star-shaped polymers with ultrahigh molecular weights from nonconjugated monomers. The photoenzymatic RAFT polymerization method offers outstanding control over composition, molecular weight, and architecture.

SourceWiley·JournalAngewandte Chemie International Edition·DateOct 27, 2020

Developing new smart soft materials

Researchers at Ehime University have successfully synthesized a new type of polymer with a carboxy-functionalized dendron structure. The polymer demonstrates pH-responsive behavior due to the dense accumulation of side chains, paving the way for the development of new functional poly(substituted methylene)s.

SourceEhime University·JournalMacromolecules·DateAug 4, 2020

Uncovering microgel mysteries

A team of scientists at Shinshu University used a newly customized tool to study hydrogel microspheres, observing structural differences that were previously unexplained. The study reveals that the method of production greatly affects the structure and behavior of thermoresponsive microgels.

SourceShinshu University·JournalAngewandte Chemie International Edition·DateMay 30, 2019

Green alternative to PET could be even greener

Researchers at the University of Groningen have developed an enzyme-based polymerization method to create a more environmentally friendly alternative to traditional polyethylene terephthalate (PET). By using a commercially available enzyme, they successfully produced furan-based copolyesters with improved properties.

SourceUniversity of Groningen·JournalChemSusChem·DateJan 30, 2019

Engineering on a blue streak

University of Delaware researchers have developed a novel method for creating interpenetrating polymeric networks using blue light, offering a more efficient and sustainable approach. This one-step process enables the formation of complex shapes without solvents or additives, resulting in enhanced toughness and reduced brittleness.

SourceUniversity of Delaware·JournalPolymer Chemistry·DateJul 28, 2017

Phosphorus rubber

Scientists have introduced a new, phosphorus-containing rubber analogue with similar properties to natural rubber. The polymerization of this compound offers prospects for further derivatization and crosslinking, enabling unique architectures and properties in commercial rubbers.

SourceWiley·JournalAngewandte Chemie International Edition·DateJul 10, 2017

Breaking the backbone

Researchers have developed a method to produce degradable polymers through chemical vapor deposition (CVD), allowing for the creation of biodegradable implants and coatings. The new polymers can be tailored to degrade at specific rates, making them suitable for various medical applications.

SourceWiley·JournalAngewandte Chemie International Edition·DateDec 1, 2016

Plastic is forever -- or not

Virginia Tech researchers have made a breakthrough in creating polymers that can be reversed using heat, opening up new possibilities for thermoplastic elastomers (TPE) and novel adhesives. The team synthesized nano-phase separated polystyrene and polyisoprene based materials containing reversible linkages.