Articles tagged with Oxidation
Researchers at BESSY II have discovered complex superstructures '29'Cu_xO, which form before pure copper oxide builds up. The oxidation state of copper in these superstructures is surprisingly close to the metallic state, contradicting conventional assumptions.
Researchers at the University of Washington have created two new spinels made of silver, chromium, and selenium ions, which exhibit magnetic properties up to 400 Kelvin. The spinels transform when exposed to air, with the original losing magnetism at a lower temperature compared to the second spinel.
Researchers have developed a nanocage architecture that seamlessly integrates ultrafast solar evaporation with selective pollutant degradation in a single material. The architecture achieves record-breaking water evaporation rates and demonstrates exceptional environmental adaptability in a single material.
Researchers found that reconstructed coal gangue can activate powerful oxidation reactions to break down persistent organic pollutants. The material's intrinsic reactivity and surface chemistry are key factors in its ability to degrade pollutants.
Researchers discovered that phosphorus plays a synergistic promoter role in evolving NiFe phosphides, accelerating oxygen evolution and suppressing dissolution of iron ions. The breakthrough catalyst delivers exceptional OER activity, achieving low overpotentials and superior reaction kinetics.
Researchers developed a stepwise nitrogen stripping strategy to create a unique metal ensemble catalyst for selective oxidation of biomass-derived 5-hydroxymethylfurfural. The catalyst achieves high yields and efficiency under mild conditions, making it an attractive alternative to traditional non-precious metal catalysts.
A review from Florida Atlantic University links obesity to Alzheimer's disease through disruptions in metabolism, highlighting the importance of mitochondrial function and gut-brain axis balance. Early detection and whole-body prevention may become possible through monitoring metabolic health.
Researchers developed a platinum-based catalyst supported on oxygen-vacancy-rich cerium oxide (Pt/CeO2–Vo) to enhance hydrogen activation. The catalyst achieved a pyrrolidone yield of 95.2% within one hour, with high formation rates and excellent stability.
Researchers at University of Wisconsin-Madison develop a systematic study for sustainable production of malonic acid via oxidation of 3-hydroxypropionic acid with a Pd/Carbon catalyst. The kinetic model validated the network, displaying excellent agreement and providing insight into conditions that maximize MA production.
Researchers provide a comprehensive framework for removing emerging contaminants from wastewater through advanced oxidation processes. Key findings highlight the importance of understanding reaction pathways to optimize treatment systems.
Researchers developed a new atomically layered material that reduces resistivity by five orders of magnitude when oxidized, exceeding similar non-layered materials. The team discovered a synergy between oxidation and structural modification driving dramatic changes in physical properties.
Researchers at Hanbat National University have developed a game-changing heat shield technology that provides dual-layer protection for high-temperature alloys. The sequential B-Si coating technology allows these alloys to withstand extremely high temperatures, potentially transforming the aviation industry.
Researchers developed a new technology that converts titanium oxide semiconductors into p-type semiconductors using just one laser process. This Laser-Induced Oxidation and Doping Integration (LODI) technology can simultaneously execute oxidation and doping, drastically shortening the traditional complex process.
Researchers at ISTA have discovered a way to tune singlet oxygen, a highly reactive ROS that causes cell damage and degrades batteries. By controlling the pH inside mitochondria, they can produce more 'good' triplet oxygen and reduce the production of 'bad' singlet oxygen.
Researchers found that bean plants and other species evolved a predisposition for the symbiosis at least three times, supporting a long-standing theory. This biological trick allows plants to access atmospheric nitrogen, boosting crop yields.
Researchers develop redox-adaptive auto-tandem catalysis using cerium to perform multiple reaction steps in a single container. This method reduces overhead and energy requirements, leading to lower costs and reduced chemical waste.
Researchers at Nagoya University developed a catalyst system that converts alcohols to valuable chemical products at lower temperatures using safer iodine compounds. The new system eliminates toxic heavy metal waste, cuts reaction temperatures by over half, and reduces energy costs.
Face masks degrade into nanoplastics under sunlight, changing their chemical nature and affecting ecosystems. Researchers found that exposure to sunlight is required for the formation of manganese oxide on plastic particles, altering their interaction and transport in the environment.
A team of Penn State researchers has discovered a fundamental reaction in transition metal chemistry that can proceed through a different order of events, achieving the same outcome. This finding raises questions about whether this new pathway has been occurring all along and potentially opens up new avenues for chemical design.
A USC study found that high levels of iron in the brain contribute to cell damage and oxidative stress, accelerating Alzheimer’s symptoms in individuals with Down syndrome. This connection could lead to targeted treatments and improved outcomes for those at risk.
Researchers at Tohoku University have developed a novel oxidation process using sonicated carbon nanotubes to remove industrial and municipal pollutants from contaminated water. The nonradical pathway achieves unprecedented removal rates within five minutes, targeting distributed water sources.
Researchers from Institute of Science Tokyo developed a novel catalyst that efficiently produces sulfones at low temperatures, achieving high selectivity and reducing precious metal consumption. The new SrMn₁₋xRu_xO₃ catalyst offers significant advantages over conventional systems, making it suitable for various industries.
Researchers at URV develop system to monitor oxidation of hazelnuts using hyperspectral camera, confirming atmosphere and light exposure as main causes of oxidation. The method allows for quality standards to be set and improves packaging techniques.
Researchers at Pennington Biomedical Research Center investigated tirzepatide's effects on weight loss and metabolic health. The study found that tirzepatide decreased calorie intake and increased fat oxidation, leading to significant weight loss. However, the drug did not decrease the slowing down of metabolic rate usually observed wi...
A study found that sediment resuspension triggered by trawling and natural processes releases significant amounts of CO2 into the atmosphere through pyrite oxidation. The research reveals that protecting sensitive seafloor areas with fine-grained sediments is crucial to maintain the region's carbon sink capacity.
Researchers developed a new ultrafine platinum-based high-entropy alloy octahedra catalyst that enhances methanol oxidation reaction activity and durability. The senary alloy outperformed ternary alloys and commercial platinum-on-carbon catalysts in terms of performance, offering a promising advance for direct methanol fuel cells.
Researchers at Aarhus University have mapped the precise structure of CD163 bound to haptoglobin-haemoglobin complex, providing unique insight into its function. This breakthrough connects earlier observations and opens up opportunities for studying the evolution of CD163's structure and interaction with other proteins.
Researchers have developed a new sensor to detect hazardous gas leaks in lithium-ion batteries, which could prevent catastrophic failures and enhance the reliability of battery-powered technologies. The sensor detects trace amounts of ethylene carbonate vapour, targeting potential battery failures before they escalate into disasters.
The review explores how antioxidant-enzyme interactions contribute to the development of non-communicable diseases, including cardiovascular disorders and cancer. Emerging therapeutic strategies harness these interactions to manage NCDs, offering potential benefits through dietary and pharmacological interventions.
Researchers found that consuming moderate amounts of curcumin can facilitate muscle recovery and alleviate pain following strenuous physical exercise. The study also confirmed curcumin's antioxidant and anti-inflammatory properties in the context of sports, with benefits including reduced muscle damage and inflammation.
A POSTECH research team found that EGF/EGF-like domains interact with GlcNAc-based biopolymers to achieve strong underwater adhesion without oxidation, leading to durable and reversible bonds.
Researchers at the University of São Paulo have discovered a way to detect peroxymonocarbonate, a potent oxidant derived from CO2, in human cells. The novel method uses fluorescent molecular probes and has implications for understanding the impact of high CO2 levels on human health.
A new Cu-doped NiCo alloy catalyst has been developed for efficient electro-oxidation of glycerol to formate, achieving high selectivity and activity at room temperature. The catalyst reduces the energy barrier and increases the Faraday efficiency for formate production.
Researchers at Tokyo Institute of Technology developed a highly selective and efficient glycerol electrooxidation process that converts waste into high-value three-carbon compounds. Higher borate concentrations improved selectivity for these products, reducing the need for additional processing.
Researchers have discovered that dialyl-sulfide and trans-chalcone can prevent breast cancer by targeting SULT1E1 and HIF1a-MMPs. These compounds neutralize oxidative stress and induce the expression of SULT1E1, leading to decreased HIF1a and MMP production.
Researchers analyzed rocks collected from seafloor, finding they date back to at least 2.5 billion years ago and have retained a stable oxidation state since then. The discovery provides new evidence on Earth's geologic history and sheds light on the planet's evolution.
A novel genus, Candidatus Alkanivoras nitrosoreducens, is described as potentially performing nitrite-driven anaerobic ethane oxidation. The study reveals a prospective fumarate addition pathway for anaerobic ethane oxidation and a complete denitrification pathway for nitrite reduction.
Researchers have found that choosing the right electrolyte significantly increases the efficiency of the glycerol oxidation reaction in PEC reactors. The study used a PEC cell with photoanodes made of nanoporous bismuth vanadate and tested acidic electrolytes, finding that certain cations and anions improve photocurrent, stability, and...
A multidisciplinary research team has developed a predictive tool for designing complex metal alloys that can withstand extreme temperatures. By analyzing the degradation of high-entropy alloys, the team discovered universal rules that can predict oxidation behavior in these alloys.
The fungus secretes enzymes that transform tea chemical components through oxidation, degradation, and condensation reactions. This results in high-quality fermented teas with enhanced flavor and health benefits.
Researchers at Tokyo University of Science have developed a novel approach to directly observe electron transfer in solids using X-ray crystal structure analysis. This breakthrough could lead to advancements in energy storage, nanotechnology, and materials science research.
This study validates a two-stage process for producing polyhydroxyalkanoates (PHA) using peanut oil and propionate with Cupriavidus necator. The findings show that peanut oil is the most beneficial carbon source, leading to increased biomass and PHA production.
Researchers at Binghamton University have developed a new 3D printing technique that uses nanotubes to reinforce additively manufactured metals, making them stronger in corrosive environments. The technique has the potential to revolutionize the field of metal manufacturing and increase U.S. competitiveness.
Researchers found that longer sprint interval training protocols, such as SIE20, outperform shorter protocols like SIE10 in increasing peripheral oxidative metabolism. This study's findings suggest that less-than-15-minute exercise regimens can provide significant health benefits.
Researchers investigate the neuroprotective effects of tocotrienols in alleviating obesity-induced cognitive decline. The study found that T3s treatment improved cognitive function and mitigated oxidative stress in mice fed with a high-fat, high-sucrose diet.
Researchers have decoded the multiple oxidation processes at the platinum-electrolyte interface in high-temperature PEM fuel cells using tender X-ray studies. The results show that variations in humidity can influence some of these processes to increase the lifetime and efficiency of fuel cells.
The study elucidates the role of interfacial cations in oxide formation on Pt surfaces, suggesting that selecting optimal cations can control surface oxidation and improve electrode durability. This finding is crucial for developing high-performance and stable Pt electrocatalysts for next-generation electrochemical devices.
Researchers have developed a copper(II)-alkylperoxo complex that can selectively oxidize unactivated alkanes, showcasing exceptional reactivity and paving the way for sustainable technology. By manipulating the solvent environment, the team uncovered the unique properties of their catalyst.
A research team has synthesized a cutting-edge manganese-fluorine catalyst with exceptional oxidizing power, capable of extracting electrons from compounds. The catalyst facilitates efficient electron loss from toxic toluene derivatives, marking a significant breakthrough in catalytic research.
Researchers at Tokyo Metropolitan University developed a method to coat gold nanoparticles on silica with a single nanosheet of mixed metal oxide, boosting their catalytic activity. The new catalyst showed significant improvements in converting carbon monoxide to carbon dioxide, outperforming existing methods.
The team developed a 'catch-and-release' mechanism to oxidize hydrophobic compounds, selectively and efficiently producing hydrophilic products under mild conditions. This breakthrough enables the selective two-electron oxidation of anthracene and aromatic compounds from mixtures, solving a long-standing challenge.
Researchers found that a thin layer of magnesium significantly improves tantalum's purity and raises its operating temperature as a superconductor. This could lead to increased quantum information retention in qubits, ultimately benefiting quantum computing.
Researchers use advanced electron microscopy and computational modeling to understand tantalum oxide formation, which can impede qubit performance. The study reveals a 'suboxide' layer at the interface between tantalum and oxide, with ordered crystalline lattice features.
A research team led by Professor Yang Yong found that severely oxidized metallic glass nanotubes can attain an ultrahigh recoverable elastic strain of up to 14% at room temperature. The discovery implies that oxidation in low-dimension metallic glass can result in unique properties for applications in sensors, medical devices, and othe...
Scientists from Osaka University and collaborators identify environmentally friendly reaction conditions for producing peracids, overcoming wasteful and dangerous chemical synthesis methods. The optimized process uses sunlight and oxygen, allowing for safe and cost-effective production of essential chemicals.
Researchers have successfully transmitted a domino effect in redox reactions for the first time. The new mechanism involves a two-part molecule that undergoes structural changes upon oxidation, triggering further oxidation in neighboring groups. This discovery has potential applications in nanoscale computing and energy systems.
Scientists at the University of California - Riverside have developed a fire-safe fuel that cannot ignite without an external electrical current. This breakthrough could significantly reduce the risk of wildfires and improve energy efficiency.
Researchers at City University of Hong Kong have developed a new class of near-infrared-activated photo-oxidants that can effectively kill cancer cells without requiring oxygen. The discovery offers a promising direction for developing anti-cancer drugs and could overcome existing limitations of photodynamic therapies.
Researchers developed a liver-targeting drug that reversed obesity and lowered cholesterol in obese mice by delivering the drug via nanogel. The treatment, which was administered intraperitoneally, effectively normalized weight and reduced cholesterol levels despite continued high-fat diet consumption.
Researchers from Tokyo Institute of Technology have developed a novel synthesis method for imine-based COFs, eliminating the need for long reaction times, high temperatures, and Lewis acid catalysts. The method uses an electrogenerated acid as a catalyst, enabling direct fixation of COF films onto electrodes.